Scientists at the University of Chicago’s Institute for Molecular Engineering (IME) and the University of Wisconsin have developed an inexpensive method for generating clean fuel is the modern-day equivalent of the philosopher’s stone. One compelling idea is to use solar energy to split water into its constituent hydrogen and oxygen and then harvest the hydrogen for use as fuel. But splitting water efficiently turns out to be not so easy.
Kyoung-Shin Choi is a professor of chemistry at the University of Wisconsin, Madison, and an experimentalist. Giulia Galli is Liew Family Professor of Electronic Structure and Simulations at the IME and a theorist.
Working together, the two scientists found a way to increase the efficiency with which an electrode used for splitting water absorbs solar photons while at the same time improving the flow of electrons from one electrode to another.
When building a sun-capturing electrode, scientists aim to use as much of the solar spectrum as possible to excite electrons in the electrode to move from one state to another, where they will be available for the water-splitting reaction. Equally important, but a separate problem entirely, the electrons need to move easily from the electrode to a counter-electrode, creating a flow of current. Until now, scientists have had to use separate manipulations to increase photon absorption and the movement of electrons in the materials they are testing.
Choi found that if they heated an electrode made of the semiconducting compound bismuth vanadate to 350 degrees Celsius while flowing nitrogen gas over it, some of the nitrogen was incorporated into the compound.
The result was a notable increase in both photon absorption and electron transport. What was not clear was exactly how the nitrogen was facilitating the observed changes. So Choi turned to Galli, a theorist, to see if her simulations of the system could provide insight into what was going on.
Galli found that the nitrogen was acting on the electrode in several ways. Heating the sample while flowing nitrogen gas is known to extract oxygen atoms from the bismuth vanadate, creating “defects.” Galli’s team found that these defects enhance the transport of electrons. But more interestingly, they found that the nitrogen that had been incorporated into the compound increased the transport of electrons independent of the defects.
Finally, that nitrogen lowered the energy needed to kick electrons into the state in which they were available to split water. This meant that more of the solar energy could be used by the electrode.
It’s axiomatic in science that experimentalists and theorists need one another. But it is actually not so common for them to collaborate from the beginning of a project as Galli’s and Choi’s teams have done. The two came together through a National Science Foundation initiative called the Center for Chemical Innovation — Solar, led by Prof. Harry B. Gray of Caltech. The center fosters scientific collaborations aimed at coming up with a device to split water.